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Are you familiar with web development by chance? Can you see anything in your browser’s developer tools like failed XHR/fetch requests? I’m kind of wondering if they’re doing something specific since you said traffic is flowing as expected on other websites.
If your VPN exits from a datacenter (common with VPN and cloud providers) it could be that while their website wasn’t smart enough to block you, the server the content streams from is and is refusing to stream the content. This would probably show up as a failure in the developer tools (HTTP 401 Unauthorized, some JSON with an error, etc).
Those websites (and tons of others) will tell you who your ISP appears to be. Whether or not a service considers it a datacenter isn’t set in stone, but usually it’s easy to tell based on what’s shown there.
Edit: If you’re getting the captchas it’s probably because you appear to be on a VPN.